[ExI] Spirited molecules
David
deimtee at optusnet.com.au
Sat Dec 5 13:08:21 UTC 2009
On Fri, 4 Dec 2009 14:55:24 -0500
Robert Bradbury <robert.bradbury at gmail.com> wrote:
> Well, I had some difficulty reading this post as I do not read the
> ExICh list frequently (due to its gestapo policies).
>
> But this topic attracted my attention.
>
> Thel unbonded "azide" molecule (with the formula CN4) does not exist
> (to the best of my knowledge to assay it). The best using Wikipedia
> that I have been able to find is possibly N3- and therefore molecules
> such as NaN3 (sodium azide). The statement by Derek with respect to a
> "Cyanogen azide" suggests a C2N2 bonded to a N4 molecule -- which I
> fail to understand (I can posit plausible explanations for the
> distribution of the electrons (around many molecules) -- but I cannot
> posit how it is created or its actual normal chemical makeup.
>
> Robert
How about a ring structure :
N=C=N-N=N- (back to the first N)
bonds add up, and it looks damn unstable to me.
-David
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